Modeling a gas mixture

The flow solver uses the scalar equation to model a gas mixed in any proportion with the main gas. The software supports up to five gases in the mixture. All gases are assumed to behave as ideal gases using the ideal gas law.

The flow solver uses the conservation equations of mass, momentum, and energy to compute the gas mixture.

When modeling a gas mixture, the following properties are calculated at every iteration:

  • ρ the gas mixture density
  • Cp the specific heat at constant pressure of the gas mixture
  • k the thermal conductivity of the gas mixture
  • μ the dynamic viscosity of the gas mixture

This property update is based on the assumption that the two gases behave as ideal gases. Ideal gas equations of state for two gases, defined as follows:

  • p1, p2 represent the partial pressures of gas 1 and gas 2.
  • R1, R2 are the gas constants of gas 1 and gas 2.

Pressure and density of the gas mixture

The pressure of the gas mixture is given by:

The density of the gas mixture is given by:

Specific heat at constant pressure of the gas mixture

The specific heat of the mixture, Cp, is calculated from the following equations [18]:

  • Ĉp is the molar specific heat of the mixture, defined as:
  • is the molar mass of the mixture, defined as:

In these equations, and are the molar masses of gas 1 and gas 2.

Thermal conductivity and dynamic viscosity of the gas mixture

The thermal conductivity, k, and the dynamic viscosity, μ, of the mixture are calculated using the method of Wilke [19], which is valid for gases at low pressures.

The property ηm, that represents the the gas mixture thermal conductivity or the gas mixture dynamic viscosity, is given by:

where ϕ12 and ϕ21 are given by:

In these equations:

  • ηm, η1, and η2 represent the property, thermal conductivity or viscosity, of the gas mixture, gas 1, and gas 2, respectively.
  • X1 and X2 are the mole fractions of the two gases given by: