Condensation and evaporation

In transient analysis, the flow solver computes condensation and evaporation at walls when the ambient fluid is air.

The model assumes film type condensation or evaporation with the following conditions:

  • The water film on the surface of the walls is very thin.
  • The temperature of the liquid film is assumed to be the same as that of the wall.
  • The rate of mass transfer between condensate and the air is small.
  • The presence of the condensate does not affect the heat transfer coefficient of the surface.

Mass and scalar conservation equations

The flow solver calculates the flux of water vapor from the film to the air as follows [13]:

If the water vapor density is greater than the density at saturation (i.e. 100% relative humidity), then the flow solver evaluates the water vapor flux from:

The mass transfer coefficient, hm, is evaluated from the Lewis relation:

  • ρB,sat(Ts) is the saturation density of water vapor at the wall temperature.
  • ρBf is the density of the water vapor in the fluid.
  • h represents the heat transfer coefficient computed by the thermal solver.
  • Cpm is the specific heat per unit volume of the air-vapor fluid mixture.
  • ρAf is the density of air in the fluid.
  • α/Dv is the ratio of the thermal diffusivity of the fluid mixture to the diffusivity of the water vapor, also called the Lewis number.

Evaporation corresponds to a positive flux of water vapor to the fluid, while condensation corresponds to a negative flux.

The flow solver uses the mass flux as a source term in both the mass and momentum equations and the scalar equation.

Energy conservation equation

The addition or retrieval of water vapor to or from the air as a result of evaporation or condensation also affects the overall enthalpy of the fluid mixture. The energy flux to the fluid mixture resulting from evaporation or condensation is evaluated as:

  • Cp,bf is the specific heat of the water vapor at the fluid temperature, Tf.

This energy flux is a source term in the energy equation.